If you try the ip 114.97.58.144 in the “diagnostics” window you can see where it is rejected by the black list IP check as well as the SFS lookup.
Either of those should have blocked the IP. IP checking is working and the IP is clearly bad for those two reasons.
The “allow options” are executed first. For instance the “Good Cache” will accept the IP and not bother to check further. Check to see if any of the allow functions will let them slip through.
It could be that the captcha is turned on and the user is correctly entering the captcha. Turn off Captcha to check.
It could be that one of the other allow options is letting the person through.
I don’t know why the code is going to admin-ajax.php. This is not standard for logins or comments.
The plugin won’t work with JetPack protection, and it won’t work with other spam plugins. It will not work with plugins that do custom logins. It does not work with woo-commerce.
The plugin is designed to work with standard WordPress installations. It cannot work if you use a plugin that bypasses the WordPress login and comment screens.
Keith