You can certainly use the Relevanssi data to find all the posts that have the word “chocolate”. Relevanssi doesn’t know the location, but you can use Relevanssi highlight all the words “chocolate” from the post, which helps.
However, book indices contain a very small fraction of the words in the book, carefully chosen only to list the most significant words. The Relevanssi index has ALL the words on the site. You can’t just take the Relevanssi index; it would be very unhelpful. You probably don’t need to know which posts have the word “need”, “example”, or “unhelpful” in them, for example.
If you create the list of words in the index yourself, you can then use the Relevanssi index to find out which posts contain the word.