With Relevanssi Premium, it would be a simple checking of the “Exclude this post from the index” checkbox from the post edit page.
With the free version, you can add a filter function on the relevanssi_do_not_index hook:
add_filter( 'relevanssi_do_not_index', 'rlv_post_exclusion', 10, 2 );
function rlv_post_exclusion( $block, $post_id ) {
$blocked_posts = array( 1, 2, 3, 4, 5 ); // List excluded post IDs here.
if ( in_array( $post_id, $blocked_posts, true ) ) {
$block = 'Excluded post';
}
return $block;
}