There’s not enough information regarding your header centering problem. But, the stretched logo problem, I have a possible fix for.
Work-Around
Add the following rule to the “Custom CSS” section of the theme (Appearance / Customiz’it!):
img { width: auto; width: auto\9; }
Cause
I took a quick look through the theme’s style sheets for each skin color (wp-content/themes/customizr/inc/css/*.css) and noticed a hack. The hack appears as a style rule that attempts to set the width for all image elements to a value of “auto\9”.
The “auto\9” value is a hack to fix a layout issue with IE 6, 7, and 8. This hack fails in the latest Chrome, version 31 (and probably previous versions), and (so far as I’ve been told) IE 10 and 11.
Explanation
Chrome 31 and IE 11 both seem to ignore the hack using my work-around. So, it should hopefully continue work with the outdated browser versions, although I haven’t tested it with them nor any other browsers. And, since the work-around goes into the custom settings for the theme, it should survive future upgrades until the theme is fixed and the work-around can be dropped.