No Ads for Annonymous?

Taxonomy for user is available only when that user is logged in.

For “Anonymous” users you probably mean not logged in users?

You can configure insertion for not logged in users:
https://adinserter.pro/documentation/additional-block-settings#insertion

I want it for All users who are NOT a certain role. Including ones not logged in.

Ive removed this filter. The “All Users” is selected and the ad does not show.

Then simply black list “certain role”.

Make sure that users do not get cached pages.

It was the cache. Thank you.

You are welcome!

The Role: user-subscribe with a blacklist of the setting above does not work to filter the role. Its showing for non-logged in users. But it is also showing for the black listed role.

What creates role user-subscribe?

Restrict Content Pro

I suggest to use debugging function Log processing to see actual data used for insertion:
https://adinserter.pro/documentation/debugging#log-processing

Check page source to see what user and user role was detected.

You can also enable remote debugging and list blocks and pages to check.