First off all I recommend you to create your own child theme for Duena (for safety editing template files, you can find tutorial here – https://codex.www.ads-software.com/Child_Themes).
Then, if you need centered content only on single post page – copy into your child theme file single.php, open it in editor and find string <div id="primary" class="span8 <?php echo esc_attr( of_get_option('blog_sidebar_pos') ) ?>">
. Then change it to
<div id="primary" class="span12 <?php echo esc_attr( of_get_option('blog_sidebar_pos') ) ?>">
If you need all pages with center content – find all files wich contains this string and replace it with <div id="primary" class="span12 <?php echo esc_attr( of_get_option('blog_sidebar_pos') ) ?>">
But it’s not good idea, because a lot of styles in theme adapted to two columns structure and some elements after that manipulations can look not good