Groups extension, and all others, are on my web site. Here’s a direct link to that extension:
https://stephensherrardplugins.com/plugins/pta-volunteer-sign-up-sheet-groups/
You should really spend at least an hour or so to familiarize yourself with basic CSS if you are trying to run a website.
The default sizes for those headings will be determined by your theme. They are H3 and H4 headings. So, if your theme already has a setting for font sizes of headings, you could modify the size there to change them globally.
Otherwise, you use the inspection feature of your browser to figure out the selector. I have added class names to almost all output my plugin generates, so it’s easy to select just a specific header or element from my plugin if you don’t want to change font sizes globally.
The classes for those two selectors are both pta-sus and user-heading (two classes). You could use either one of them as a selector to change font size like this:
h3.pta-sus { font-size:16px;}
h4.pta-sus { font-size:14px;}
You can set the font-size to whatever you want, with any acceptable units (do a search… it’s very easy to find all the options, and many tutorials).