To me, (not on MU), it occurs when your’re viewing the site without being logged-in. Because when a user isn’t logged in the Global $wp_roles
is empty.
As a workaround, i had edited the user-role-editor.php,
@line: 181 you’ll have the ure_init()
function.
inside of it, the test for: if (!$role->has_cap(URE_KEY_CAPABILITY)) {
i’d put that entire block inside a if, to test if we had a user logged in.