The only thing I can think of, other than using the export and import abilities under tools, would be this plugin… https://www.ads-software.com/plugins/wp-multisite-content-copier/
For ongoing synchronization, you might try this plugin which isn’t supported anymore but may still work since it mostly relies on the built-in XML-RPC capabilities in WordPress.
https://www.ads-software.com/plugins/syndicate-out/
I’d be slightly concerned about security with this plugin but you can obviate a lot of those concerns by running something like WordFence and iThemes Security together.
https://www.ads-software.com/plugins/wordfence/
and
https://www.ads-software.com/plugins/better-wp-security/
Those two security plugins behave well together and compliment each other.