No problem. WordPress is pulling your title from the options menu. You can just insert your title into the header manually and add a span tag around the first word so that you can customize the first and second words differently.
Go to Presentation > Theme Editor > Header
Find <?php bloginfo(‘name’); ?> towards the bottom
Replace with <span id=”firstWord”>First</span> Second
Then you can reference the id in your stylesheet which is also found in the theme editor like #firstWord {color: red;}